FRIEDELAN-3b-OL 
FRIEDELAN-3b-OL
RMN de 1H 400 MHz (CDCl3/C5D5N) |
Atrib |
d |
Mult |
J |
Atrib |
d |
Mult |
J |
1eq |
1,45 | m (1H) |
16 |
1,18 e 1,46 | m (2H) |
|||
1ax |
1,69 | td (1H) |
13,0; 3,0 |
18ax |
1,56 | dd (1H) |
11,0; 6,0 |
|
2ax |
1,56 | m (1H) |
19 |
1,21 e 1,37 | m (2H) |
|||
2eq |
1,99 | dq (1H) |
13,0; 3,0 |
21 |
1,28 e 1,49 | m (2H) |
||
3 |
3,81 | q (1H) |
2,0 |
22ax |
0,93 | dd (1H) |
12,0; 2,0 |
|
4 |
1,25 | m (1H) |
22eq |
1,49 | m (1H) |
|||
6ax |
0,99 | m (1H) |
23 |
1,02 | d (3H) |
6,0 |
||
6eq |
1,76 | dt (1H) |
12,0; 3,0 |
24 |
1,10 | s (3H) |
||
7 |
1,39 e 1,41 | m (2H) |
25 |
0,89 | s (3H) |
|||
8 |
1,28 | m(1H) |
26 |
0,99 | s (3H) |
|||
10ax |
0,93 | dd (1H) |
12,0; 2,0 |
27 |
1,02 | s (3H) |
||
11 |
1,24 e 1,42 | m (2H) |
28 |
1,18 | s (3H) |
|||
12 |
1,31 e 1,34 | m (2H) |
29 |
0,97 | s (3H) |
|||
15ax |
1,53 | m (1H) |
30 |
1,02 | s (3H) |
|||
15eq |
1,28 | m (1H) |
| RMN de 13C 100 MHz (CDCl3/C5D5N) | C |
d |
C |
d |
C |
d |
1 |
16,16 | 11 |
35,66 | 21 |
32,88 | |
2 |
36,14 | 12 |
30,69 | 22 |
39,28 | |
3 |
71,59 | 13 |
38,38 | 23 |
12,09 | |
4 |
49,62 | 14 |
39,69 | 24 |
16,58 | |
5 |
38,09 | 15 |
32,34 | 25 |
18,35 | |
6 |
41,99 | 16 |
35,90 | 26 |
20,13 | |
7 |
17,69 | 17 |
30,02 | 27 |
18,69 | |
8 |
53,27 | 18 |
42,88 | 28 |
32,12 | |
9 |
37,18 | 19 |
35,36 | 29 |
35,02 | |
10 |
61,65 | 20 |
28,17 | 30 |
31,85 |
Resonance Magnetic in Chemistry, 38(11), 977-980,2000.
